Sulfuric Acid Manufacture Analysis control and optimization 2nd Edition by Matt King, Michael Moats, William G. Davenport – Ebook PDF Instant Download/Delivery: 0080982204, 978-0080982205
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Product details:
ISBN 10: 0080982204
ISBN 13: 978-0080982205
Author: Matt King, Michael Moats, William G. Davenport
By some measure the most widely produced chemical in the world today, sulfuric acid has an extraordinary range of modern uses, including phosphate fertilizer production, explosives, glue, wood preservative and lead-acid batteries. An exceptionally corrosive and dangerous acid, production of sulfuric acid requires stringent adherence to environmental regulatory guidance within cost-efficient standards of production.
This work provides an experience-based review of how sulfuric acid plants work, how they should be designed and how they should be operated for maximum sulfur capture and minimum environmental impact. Using a combination of practical experience and deep physical analysis, Davenport and King review sulfur manufacturing in the contemporary world where regulatory guidance is becoming ever tighter (and where new processes are being required to meet them), and where water consumption and energy considerations are being brought to bear on sulfuric acid plant operations. This 2e will examine in particular newly developed acid-making processes and new methods of minimizing unwanted sulfur emissions.
The target readers are recently graduated science and engineering students who are entering the chemical industry and experienced professionals within chemical plant design companies, chemical plant production companies, sulfuric acid recycling companies and sulfuric acid users. They will use the book to design, control, optimize and operate sulfuric acid plants around the world.
Unique mathematical analysis of sulfuric acid manufacturing processes, providing a sound basis for optimizing sulfuric acid manufacturing processes
Analysis of recently developed sulfuric acid manufacturing techniques suggests advantages and disadvantages of the new processes from the energy and environmental points of view
Analysis of tail gas sulfur capture processes indicates the best way to combine sulfuric acid making and tailgas sulfur-capture processes from the energy and environmental points of view
Draws on industrial connections of the authors through years of hands-on experience in sulfuric acid manufacture
Table of contents:
1 Production and consumption
2 Sulfur burning
3 Metallurgical offgas cooling and cleaning
4 Regeneration of spent sulfuric acid
5 Dehydrating air and gases with strong sulfuric acid
6 Catalytic oxidation of SO2 to SO3
7 SO2 oxidation catalyst and catalyst beds
8 Materials of construction
9 Costs of sulfuric acid production
10 Sulfuric acid properties
11 Derivation of equilibrium equation 1012
12 Free energy equations for equilibrium curve calculations
13 Preparation of Fig 102 equilibrium curve
14 Proof that volumemol for ideal gases
15 Effect of CO2 and Ar on equilibrium equations none
SO2 to SO3 conversion process
16 Production of H2SO4 from SO3
17 Break
18 Oxidation of SO2 to SO3 Equilibrium curves
19 SO2 oxidation heatup paths
20 Maximum SO2 oxidation Heatup path equilibrium curve intercepts
21 Cooling first catalyst bed exit gas
22 Second catalyst bed heatup path
23 Maximum SO2 oxidation in a second catalyst bed
24 Third catalyst bed SO2 oxidation
25 SO3 and CO2 in feed gas
26 Three catalyst bed acid plant
27 After H2SO4 making SO2 oxidation
28 Optimum double contact acid making
29 Enthalpies and enthalpy transfers
30 Control of gas temperature by bypassing
31 H2SO4 making
32 Acid temperature control and heat recovery
33 Making sulfuric acid from wet feed gas
34 Wet sulfuric acid process fundamentals
35 SO3 gas recycle for high SO2 concentration gas treatment
36 Sulfur from tail gas removal processes
37 Minimizing sulfur emissions
Thermodynamic equations and calculation methods
38 Enthalpy equations for heatup path calculations
39 Matrix solving using Tables 112 and 142 as examples
40 Enthalpy equations in heatup path matrix cells
41 Heatup path equilibrium curve intercept calculations
42 Second catalyst bed heatup path calculations
43 Equilibrium equation for multicatalyst bed SO2 oxidation
44 Second catalyst bed intercept calculations
45 Third catalyst bed heatup path worksheet
46 Third catalyst bed intercept worksheet
47 Effect of SO3 in Fig 101 feed gas on equilibrium equations
48 SO3 in feed gas intercept worksheet
49 CO2 and SO3 in feed gas intercept worksheet
50 Three catalyst bed converter calculations
51 Worksheet for calculating after intermediate H2SO4 making heatup path equilibrium curve intercepts
52 After H2SO4 making SO2 oxidation with SO3 and CO2 in input gas
53 Moist air in H2SO4 making calculations
54 Calculation of H2SO4 making tower mass flows
55 Equilibrium equations for SO2 O2 H2O N2 feed gas
56 Cooled first catalyst bed exit gas recycle calculations
57 Answers to numerical problems
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Matt King,Michael Moats,William Davenport,Sulfuric Acid,Manufacture Analysis


