Principles of Polymerization 4th Edition by George Odian ISBN 9780471274001 0471274003

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Product details: 

ISBN 10: 0471274003

ISBN 13: 9780471274001

Author:  George Odian

Principles of Polymerization is widely regarded as the definitive textbook on polymer science, especially in the field of polymerization. This fourth edition continues to be the go-to reference for both students and professionals, offering comprehensive and up-to-date coverage of the principles, mechanisms, kinetics, and applications of polymerization processes.

This edition includes significant updates and expansions in areas such as:

Controlled/”Living” polymerizations

Ionic and radical polymerization mechanisms

Ring-opening and step-growth polymerization

Copolymerization techniques

Stereochemistry and tacticity

Emulsion polymerization and industrial processes

The book maintains a strong emphasis on kinetics and thermodynamics, equipping readers with the theoretical tools needed to understand how polymerizations proceed and how to control them. It also delves into the practical aspects of polymer production and the reactions of polymers, including crosslinking, degradation, and modification.

Table of contents: 

1. Introduction
1-1 Types of Polymers and Polymerizations

1-2 Nomenclature of Polymers

1-3 Linear, Branched, and Crosslinked Polymers

1-4 Molecular Weight

1-5 Physical State

1-6 Applications of Polymers

References

2. Step Polymerization
2-1 Reactivity of Functional Groups

2-2 Kinetics of Step Polymerization

2-3 Accessibility of Functional Groups

2-4 Equilibrium Considerations

2-5 Cyclization versus Linear Polymerization

2-6 Molecular Weight Control in Linear Polymerization

2-7 Molecular Weight Distribution in Linear Polymerization

2-8 Process Conditions

2-9 Multichain Polymerization

2-10 Crosslinking

2-11 Molecular Weight Distributions in Nonlinear Polymerizations

2-12 Crosslinking Technology

2-13 Step Copolymerization

2-14 High-Performance Polymers

2-15 Inorganic and Organometallic Polymers

2-16 Dendritic (Highly Branched) Polymers

2-17 Miscellaneous Topics

References

3. Radical Chain Polymerization
3-1 Nature of Radical Chain Polymerization

3-2 Structural Arrangement of Monomer Units

3-3 Rate of Radical Chain Polymerization

3-4 Initiation

3-5 Molecular Weight

3-6 Chain Transfer

3-7 Inhibition and Retardation

3-8 Determination of Absolute Rate Constants

3-9 Energetic Characteristics

3-10 Autoacceleration

3-11 Molecular Weight Distribution

3-12 Effect of Pressure

3-13 Process Conditions

3-14 Specific Commercial Polymers

3-15 Living Radical Polymerization

3-16 Other Polymerizations

References

4. Emulsion Polymerization
4-1 Description of Process

4-2 Quantitative Aspects

4-3 Other Characteristics of Emulsion Polymerization

References

5. Ionic Chain Polymerization
5-1 Comparison of Radical and Ionic Polymerizations

5-2 Cationic Polymerization of the Carbon–Carbon Double Bond

5-3 Anionic Polymerization of the Carbon–Carbon Double Bond

5-4 Block and Other Polymer Architectures

5-5 Distinguishing Between Radical, Cationic, and Anionic Polymerizations

5-6 Carbonyl Polymerization

5-7 Miscellaneous Polymerizations

References

6. Chain Copolymerization
6-1 General Considerations

6-2 Copolymer Composition

6-3 Radical Copolymerization

6-4 Ionic Copolymerization

6-5 Deviations from Terminal Copolymerization Model

6-6 Copolymerizations Involving Dienes

6-7 Other Copolymerizations

6-8 Applications of Copolymerization

References

7. Ring-Opening Polymerization
7-1 General Characteristics

7-2 Cyclic Ethers

7-3 Lactams

7-4 N-Carboxy-α-Amino Acid Anhydrides

7-5 Lactones

7-6 Nitrogen Heterocyclics

7-7 Sulfur Heterocyclics

7-8 Cycloalkenes

7-9 Miscellaneous Oxygen Heterocyclics

7-10 Other Ring-Opening Polymerizations

7-11 Inorganic and Partially Inorganic Polymers

7-12 Copolymerization

References

8. Stereochemistry of Polymerization
8-1 Types of Stereoisomerism in Polymers

8-2 Properties of Stereoregular Polymers

8-3 Forces of Stereoregulation in Alkene Polymerizations

8-4 Traditional Ziegler–Natta Polymerization of Nonpolar Alkene Monomers

8-5 Metallocene Polymerization of Nonpolar Alkene Monomers

References

9. Reactions of Polymers
9-1 Types of Polymer Reactions

9-2 Mechanisms and Kinetics

9-3 Applications

References

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