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Kinetics of Homogeneous Multistep Reactions 1st Edition by Helfferich ISBN 978-0080535265 0080535265

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Kinetics of Homogeneous Multistep Reactions 1st Edition F.G. Helfferich (Eds.) Digital Instant Download

Author(s): F.G. Helfferich (Eds.)
ISBN(s): 9780444826060, 0444826068
Edition: 1
File Details: PDF, 18.52 MB
Year: 2001
Language: english
SKU: EB-1129354 Category: Tag:

Kinetics of Homogeneous Multistep Reactions 1st Edition by F.G. Helfferich – Ebook PDF Instant Download/Delivery:  978-0080535265, 0080535265 
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Product details: 

ISBN 10:  0080535265 

ISBN 13:  978-0080535265

Author: F.G. Helfferich

This book addresses primarily the chemist and engineer in industrial research and process development, where competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such scale-up should be based on “fundamental” kinetics, that is, mathematics that reflect the elementary steps of which the reactions consist. The book forges fundamental kinetics into a practical tool by presenting new effective methods for elucidation of mechanisms and reduction of mathematical complexity without unacceptable sacrifice in accuracy.

Table of contents: 

  • Preface

  • Introduction

  • References

  • Concepts, Definitions, Conventions, and Notation

  • Classification of Reactions

  • Steps, Pathways, Networks, and Cycles

  • Rates

  • Rate Equations and Activation Energies

  • Orders, Molecularities, and Ranks

  • Conversion, Yield, and Selectivity

  • Summary

  • References

Fundamentals

  • Statistical Basis: Molecularities and Reaction Orders

  • Nonideality

  • Temperature Dependence

  • Compilation of Rate Equations of Multistep Reactions

  • Consistency Criteria

  • Summary

  • References

Determination of Rates, Orders, and Rate Coefficients

  • Research Reactors

  • Analytical Support

  • Reaction Orders and Apparent Rate Coefficients

  • Numerical Work-Up, Error Recognition, and Reliability

  • Summary

  • References

Tools for Reduction of Complexity

  • Rate-Controlling Steps

  • Quasi-Equilibrium Steps

  • Quasi-Stationary States: The Bodenstein Approximation

  • Relative Abundance in Catalysis and Polymerization and Long-Chain Approximation

  • Summary

  • References

Elementary Step Combinations

  • Reversible Reactions

  • Parallel Steps

  • Coupled Parallel Steps

  • Sequential Steps

  • Competing Steps

  • Reactions with Fast Pre-Dissociation

  • General Solution for First-Order Networks

  • Summary

  • References

Practical Mathematics of Multistep Reactions

  • Simple and Non-Simple Pathways and Networks

  • Pseudo-First Order Rate Coefficients

  • Simple Pathways

  • Simple Networks

  • Non-Simple Pathways and Networks

  • Summary

  • References

Network Elucidation

  • Order and Rank

  • “One Plus” Rate Equations

  • Relationships Between Network Properties and Kinetic Behavior

  • Other Criteria and Guidelines

  • Auxiliary Techniques

  • Summary

  • References

Homogeneous Catalysis

  • Single-Species Catalysis

  • Complex Catalysis

  • Classical Models of Enzyme Kinetics

  • General Formula for Single Catalytic Cycles: Christiansen Mathematics

  • Reduction of Complexity

  • Relationships Between Pathway Properties and Kinetic Behavior

  • Cycles with External Reactions

  • Multiple Cycles

  • Competing Reactions (Cycles with Common Members)

  • Dual- and Multiple-Form Catalysts (Connected Cycles)

  • Reactions with Multiple Products (Cycles with Common Pathway Segments)

  • Self-Accelerating Reactions (Autocatalysis)

  • Analogies to Heterogeneous Catalysis

  • Summary

  • References

Chain Reactions

  • General Properties

  • Initiation

  • Reactions with Two Chain Carriers: The Hydrogen-Bromide Reaction

  • Identification of Relevant Steps

  • Transmission of Reactivity: Indirect Initiation, Chain Transfer

  • Reactions with More than Two Free Radicals

  • Inhibition and Induction Periods

  • Summary

  • References

Polymerization

  • Types of Polymerization Reactions

  • Step-Growth Polymerization

  • Free-Radical Polymerization

  • Ionic Polymerization

  • Coordination Polymerization

  • Chain-Growth Copolymerization

  • Summary

  • References

Mathematical Modeling

  • Strategies of Process Development

  • Effective Mathematical Modeling

  • “Shortsightedness” of Elementary Reaction Steps

  • Model Validation

  • Summary

  • References

Unusual Thermal and Mass-Transfer Effects

  • Anomalous Temperature Dependence

  • Uncommon Heat-Transfer Problems

  • Uncommon Mass-Transfer Problems

  • Summary

  • References

  • Glossary of Symbols

  • Author Index

  • Subject Index

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Tags: Helfferich, Kinetics of Homogeneous, Multistep Reactions