In Situ Synthesis of Polymer Nanocomposites 1st Edition by Vikas Mittal ISBN 978-3527328796 3527328793

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Product details: 

ISBN 10:   3527328793

ISBN 13: 978-3527328796

Author: Vikas Mittal

The book series “Polymer Nano-, Micro- and Macrocomposites” provides complete and comprehensive information on all important
aspects of polymer composite research and development, including, but not limited to synthesis, filler modification, modeling, characterization as well as application and commercialization issues. Each book focuses on a particular topic and gives a balanced in-depth overview of the respective subfi eld of polymer composite science and its relation to industrial applications. With the books the readers obtain dedicated resources with information relevant to their research, thereby helping to save time and money.
In-situ intercalative polymerization in the presence of filler provides distinct advantages when compared to other nanocomposite synthesis
techniques including the possibility to polymerize a large range of thermoplastic and thermosetting polymers, improved handling of gaseous
or liquid monomers or high pressure polymerization and improved control of heat of polymerization. This volume aims to highlight these
advantages of the generation of polymer nanocomposites with a large spectrum of polymer matrices. Following an overview of the synthesis
methodologies, the text goes on to discuss the most relevant polymer materials, including polyamides, polyolefi nes, polyacrylates, polyethylenes, polyurethanes, polyesters and polyepoxides.

Table of contents: 

1 In-situ Synthesis of Polymer Nanocomposites
Vikas Mittal
1.1 Introduction
1.2 Synthesis Methods
1.3 In-situ Synthesis of Polymer Nanocomposites
References

2 Polyamide Nanocomposites by In-situ Polymerization
Anastasia C. Boussia, Stamatina N. Vouyiouka, and Constantine D. Papaspyrides
2.1 Introduction
2.2 Manufacturing Processes of Commercially Important Polyamides
2.2.1 Poly(caproamide) (PA 6)
2.2.2 Poly(hexamethylene adipamide) (PA 6.6)
2.2.3 Low-Temperature Polymerization Processes
2.3 Polyamide Nanocomposites
2.3.1 Introduction
2.3.2 Lactam/Amino Acid-Based In-situ Intercalated PA Nanocomposites
2.3.3 Diamine- and Diacid-Based In-situ Intercalated PA Nanocomposites
2.3.3.1 Solution-Melt Polymerization Technique
2.3.3.2 Anhydrous Melt Polymerization Technique
2.3.3.3 Direct SSP Technique
2.3.3.4 Interfacial Polycondensation Technique
2.4 Conclusions
References

3 Polyolefin-Clay Nanocomposites by In-situ Polymerization
Abolfazl Maneshi, João Soares, and Leonardo Simon
3.1 Introduction
3.2 Clays
3.2.1 General Structure
3.2.2 Smectites
3.2.3 Clay Particle Morphological Hierarchy
3.2.4 Clay Chemical Reactions
3.2.4.1 Cation Exchange Reactions
3.2.4.2 Interaction with Organic Compounds
3.3 In-situ Polymerization of Olefins with Coordination Catalysts Supported on Clays
3.3.1 Olefin Polymerization with Coordination Catalysts
3.3.2 Polymerization Mechanism with Coordination Catalysts
3.3.3 Coordination Catalysts for In-situ Polymerization
3.3.4 Catalyst Supporting
3.3.4.1 Catalyst Supporting Methods
3.3.5 Clay Surface Modification Methods for In-situ Polymerization
3.3.5.1 Organic Modification
3.3.5.2 Thermal Treatment
3.3.5.3 Treatment with Alkylaluminum Compounds
3.3.6 Particle Break-Up and Exfoliation
3.3.7 In-situ Polymerization Approaches
3.3.7.1 Clay as a Polymerization Additive
3.3.7.2 Clay as a Polymerization Catalyst Support
3.3.7.3 Clay as an Activator for Polymerization Catalysts
3.3.7.4 In-situ Production of Alkylaluminoxanes
3.3.7.5 Other Techniques
3.3.8 Factors Determining the Success of In-situ Polymerization
3.3.8.1 Clay Type
3.3.8.2 Swellability
3.3.8.3 Effect of Clay Surface Treatment
3.3.8.4 Catalyst: Clay Ratio
3.3.8.5 Effect of Polymerization Conditions
3.3.9 Clay Effect on the Polymerization Behavior and Polymer Molecular Structure
3.3.10 Future Approaches
References

4 Gas-Phase-Assisted Surface Polymerization and Thereby Preparation of Polymer Nanocomposites
Haruo Nishida, Yoshito Andou, and Takeshi Endo
4.1 Introduction
4.2 In-situ Polymerization for Nanocomposite Preparation
4.3 Characteristics of GASP
4.3.1 Thin Layer Coating of Solid-Substrate Surfaces
4.3.2 Physically Controlled Polymerization Behavior
4.3.3 Photo-Induced Controlled Polymerization
4.4 Composite Preparation by GASP
4.4.1 Polymer/Clay Nanocomposites
4.4.2 Polymer/Inorganic Compound (Nano)composites
4.4.3 Polymer/Cellulose Fiber (Nano)composites
4.4.4 Polymer/Carbon Nanotube (Nano)composites
4.5 Outlook and Perspective
Abbreviations
References

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Tags: Vikas Mittal, In Situ Synthesis, Polymer Nanocomposites