Electron Transfer Mechanisms and Applications 1st Edition by Shunichi Fukuzumi – Ebook PDF Instant Download/Delivery: 9783527326662, 3527326669
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Product details:
ISBN 10: 3527326669
ISBN 13: 9783527326662
Author: Shunichi Fukuzumi
Written by one of the top scientists in this field, this is a systematic overview of the fundamental concepts and powerful applications.
The author presents the central theories and mechanisms in electron transfer, followed by several systems in nature where this is important, while also covering modern green applications.
An invaluable resource for graduate students and researchers working in this field in academia and industry.
Table of contents:
1. Introduction
2. Marcus Theory of Electron Transfer
3. Photosynthetic Reaction Center Models
4. Electron Donor–Acceptor Dyads
5. Supramolecular Electron Transfer
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5.1 Cation–Anion Binding
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5.2 π-Complexes
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5.3 Electron-Transfer Switching
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5.4 Dendrimers
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5.5 Supramolecular Solar Cells
6. Effects of Metal Ions on Photoinduced Electron Transfer
7. Photoredox Catalysis
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7.1 Photocatalytic Oxygenation
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7.2 Photocatalytic Oxibromination
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7.3 Carbon–Carbon Bond Formation
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7.4 DNA Cleavage
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7.5 Anti-Markovnikov Hydroetherification
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7.6 Photocatalytic Cycloaddition
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7.7 Photocatalytic Hydrotrifluoromethylation
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7.8 Photocatalytic Hydrogen Evolution
8. Hydrogen Storage
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8.1 Interconversion Between Hydrogen and Formic Acid
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8.2 Interconversion Between Hydrogen and NADH
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8.3 Hydrogen Evolution from Alcohols
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8.4 Hydrogen Evolution from Paraformaldehyde
9. Metal Ion-Coupled Electron Transfer (MCET)
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9.1 MCET of O₂
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9.2 Binding Modes of Metal Ions
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9.3 Self-Organized MCET
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9.4 Accelerating and Decelerating Effects of Metal Ions
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9.5 Driving Force Dependence of MCET Rate Constants
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9.6 MCET Coupled with Hydrogen Bonding
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9.7 MCET Catalysis
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9.7.1 Hydride Transfer vs. Cycloaddition
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9.7.2 Suproxode Dismutase (SOD) Models
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9.8 MCET of Metal-Oxo Complexes
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9.9 PCET of Metal-Oxo Complexes
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9.10 Unified Mechanism of MCET and PCET of Metal-Oxo Complexes
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9.11 MCET of Metal-Peroxo Complexes
10. Catalytic Reduction of O₂
11. Catalytic Oxidation of H₂O
12. Production of Hydrogen Peroxide from Water and Oxygen as a Solar Fuel
13. Production and Usage of Hydrogen Peroxide as a Solar Fuel in Seawater
14. Photosystem II Mimic
15. Conclusion and Perspective
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Tags: Shunichi Fukuzumi, Electron Transfer, Mechanisms and Applications


