Domino Reactions Concepts for Efficient Organic Synthesis 1st Edition by Lutz Tietze ISBN 3527334327 978-3527334322

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Product details: 

ISBN 10: 3527334327 

ISBN 13: 978-3527334322

Author: Lutz F. Tietze

The follow-up to the successful “Domino Reaction in Organic Synthesis”, this ready reference brings up to date on the original concept. The chapters have been arranged according to the name of well-known transformations of the first step and in combination with the formed products. Each chapter is written by an internationally renowned expert, and the book is edited by L. F. Tietze, who established the concept of domino reactions.

The one-stop source for all synthetic chemists to improve the synthetic efficiency and allow an ecologically and economically beneficial preparation of every chemical compound.

Table of contents: 

1. Transition Metal-Catalyzed Carbonylative Domino Reactions
1.1 Introduction
1.2 Transition Metal-Catalyzed Carbonylative Domino Reactions
1.3 Outlook

2. Metathesis Reactions in Domino Processes
2.1 Domino Processes Featuring Solely Metathesis Events
2.2 Domino Processes Featuring Metathesis and Non-Metathesis Events
2.3 Conclusion and Outlook

3. C-H Activation Reactions in Domino Processes
3.1 Heck Reactions/C-H Activations
3.2 Carbopalladations and Aminopalladations of Alkynes/C-H Activations
3.3 Palladium-Catalyzed/Norbornene-Mediated ortho C-H Activations
3.4 Domino Reactions Involving Heteroatom-Directed C-H Activations
3.5 Conclusions

4. Domino Reactions Initiated by Nucleophilic Substitution
4.1 Domino SN/Michael Addition and Related Reactions
4.2 Domino Reactions Initiated by Nucleophilic Ring Opening of Aziridines, Epoxides and Activated Cyclopropanes
4.3 Domino SN/Brook Rearrangements

5. Radical Reactions in Domino Processes
5.1 Introduction
5.2 Radical/Cation Domino Processes
5.3 Radical/Anionic Domino Processes
5.4 Domino Radical/Radical Process
5.5 Radical/Pericyclic Domino Processes
5.6 Asymmetric Radical Domino Processes
5.7 Conclusion and Outlook

6. Pericyclic Reactions in Domino Processes
6.1 Introduction
6.2 Cycloadditions
6.3 Sigmatropic Rearrangements
6.4 Electrocyclizations
6.5 Mixed Transformations
6.6 Concluding Remarks

7. Modern Domino Reactions Containing a Michael Addition Reaction
7.1 Introduction
7.2 Formation of Acyclic Products
7.3 Formation of Carbocycles
7.4 Formation of O-Heterocycles
7.5 Formation of N-Heterocycles
7.6 Formation of S-Heterocycles
7.7 Formation of Heterocycles Containing Nitrogen and Oxygen

8. Aldol Reactions in Domino Processes
8.1 Introduction
8.2 Domino Processes with the Aldol Reaction as First Step
8.3 Domino Processes with the Aldol Reaction as Subsequent Step
8.4 Conclusion and Outlook

9. Oxidations and Reductions in Domino Processes
9.1 Introduction
9.2 Domino Reactions Initiated by Oxidation or Reduction Reaction
9.3 Domino Reactions Having Oxidation in Middle of the Sequence
9.4 Domino Reactions Terminated by Oxidation or Reduction Reaction
9.5 Conclusion

10. Organocatalysis in Domino Processes
10.1 Introduction
10.2 One and Two-Component Domino Reactions
10.3 Multicomponent Reactions
10.4 Conclusions

11. Metal-Catalyzed Enantio- and Diastereoselective C-C Bond Forming Reactions in Domino Processes
11.1 Domino Reaction Initiated by C-C Bond Formation
11.2 Domino Reaction Initiated by C-H Bond Formation
11.3 Domino Reaction Initiated by C-N Bond Formation
11.4 Domino Reaction Initiated by C-O Bond Formation
11.5 Domino Reaction Initiated by C-B and C-Si Bond Formation
11.6 Conclusion and Outlook

12. Domino Processes Under Microwave Irradiation, High Pressure, and in Water
12.1 Introduction
12.2 Microwave-Assisted Domino Reactions
12.3 Aqueous Domino Reactions
12.4 High-Pressure-Promoted Domino Reactions
12.5 Conclusion and Outlook

13. Domino Reactions in Library Synthesis
13.1 Introduction
13.2 Domino Reactions in Natural-Product-Inspired Compound Collection Syntheses
13.3 Domino Approaches Targeting Scaffold Diversity
13.4 Solid-Phase Domino Syntheses of Compound Collections
13.5 Conclusion

14. Domino Reactions in the Total Synthesis of Natural Products
14.1 Cationic Domino Reactions
14.2 Anionic Domino Reactions
14.3 Radical Domino Reactions
14.4 Pericyclic Domino Reactions
14.5 Transition-Metal-Catalyzed Domino Reactions
14.6 Domino Reactions Initiated by Oxidation or Reduction
14.7 Conclusion

15. Multicomponent Domino Process: Rational Design and Serendipity
15.1 Introduction
15.2 Basic Considerations of MCRs
15.3 Substrate-Design Approach in the Development of Novel MCRs
15.4 Conclusion

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Tags: Lutz Tietze, Domino Reactions, Concepts for Efficient, Organic Synthesis