Catalysis without Precious Metals 1st Edition by Morris Bullock ISBN 978-3527323548 3527323546

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Product details: 

ISBN 10:  3527323546

ISBN 13:  978-3527323548

Author:  R. Morris Bullock 

Written for chemists in industry and academia, this ready reference and handbook summarizes recent progress in the development of new catalysts that do not require precious metals. The research thus presented points the way to how new catalysts may ultimately supplant the use of precious metals in some types of reactions, while highlighting the remaining challenges.
An essential copanion for organic and catalytic chemists, as well as those working with/on organometallics and graduate students.

From the contents:

* Catalysis Involving the H’ Transfer Reactions of First-Row Transition Metals
* Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum Complexes
* Molybdenum and Tungsten Catalysts for Hydrogenation, Hydrosilylation and Hydrolysis
* Iron in Catalytic Alkene and Carbonyl Hydrogenation Reactions
* Olefin Oligomerizations and Polymerizations Catalyzed by Iron and Cobalt Complexes
* Cobalt and Nickel Catalyzed Reactions Involving C-H and C-N Activation Reactions
* Development of Molecular Electrocatalysts for H2 Oxidation and Production Based on Inexpensive Metals
* Nickel-Catalyzed Reductinve Couplings and Cyclizations
* Copper-Catalyzed Ligand Promoted Ullmann-Type Coupling Reactions
* Copper-Catalyzed Azide-Alkyne Cycloaddition
* “Frustrated Lewis Pairs”: A Metal-Free Strategy for Hydrogenation Catalysis

Table of contents: 

1. Catalysis Involving the H• Transfer Reactions of First-Row Transition Metals

2. H• Transfer Between M–H Bonds and Organic Radicals

3. H• Transfer Between Ligands and Organic Radicals

4. H• Transfer Between M–H and C–C Bonds

5. Chain Transfer Catalysis

6. Catalysis of Radical Cyclizations

7. Competing Methods for the Cyclization of Dienes

8. Summary and Conclusions

9. Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum

10. Introduction

11. Some Characteristics of Triamidoamine Complexes

12. Possible [HIPTN₃N]Mo Intermediates in a Catalytic Reduction of Molecular Nitrogen

13. Interconversion of Mo(NH₃) and Mo(N₂)

14. Catalytic Reduction of Dinitrogen

15. MoH and Mo(H₂)

16. Ligand and Metal Variations

17. Comments

18. Molybdenum and Tungsten Catalysts for Hydrogenation, Hydrosilylation and Hydrolysis

19. Introduction

20. Proton Transfer Reactions of Metal Hydrides

21. Hydride Transfer Reactions of Metal Hydrides

22. Stoichiometric Hydride Transfer Reactivity of Anionic Metal Hydride Complexes

23. Catalytic Hydrogenation of Ketones with Anionic Metal Hydrides

24. Ionic Hydrogenation of Ketones Using Metal Hydrides and Added Acid

25. Ionic Hydrogenations from Dihydrides: Delivery of the Proton and Hydride from One Metal

26. Catalytic Ionic Hydrogenations with Mo and W Catalysts

27. Mo Phosphine Catalysts with Improved Lifetimes

28. Tungsten Hydrogenation Catalysts with N-Heterocyclic Carbene Ligands

29. Catalysts for Hydrosilylation of Ketones

30. Cp₂Mo Catalysts for Hydrolysis, Hydrogenations and Hydrations

31. Conclusion

32. Modern Alchemy: Replacing Precious Metals with Iron in Catalytic Alkene and Carbonyl Hydrogenation Reactions

33. Introduction

34. Alkene Hydrogenation

35. Carbonyl Hydrogenation

36. Outlook

37. Olefin Oligomerizations and Polymerizations Catalyzed by Iron and Cobalt Complexes Bearing Bis(imino)pyridine Ligands

38. Introduction

39. Precatalyst Synthesis

40. Precatalyst Activation and Catalysis

41. The Active Catalyst and Mechanism

42. Other Applications

43. Conclusions and Outlook

44. Cobalt and Nickel Catalyzed Reactions Involving C–H and C–N Activation Reactions

45. Introduction

46. Catalysis with Cobalt

47. Catalysis with Nickel

48. A Modular Approach to the Development of Molecular Electrocatalysts for H₂ Oxidation and Production Based on Inexpensive Metals

49. Introduction

50. Concepts in Catalyst Design Based on Structural Studies of Hydrogenase Enzymes

51. A Layered or Modular Approach to Catalyst Design

52. Using the First Coordination Sphere to Control the Energies of Catalytic Intermediates

53. Using the Second Coordination Sphere to Control the Movement of Protons between the Metal and the Exterior of the Molecular Catalyst

54. Integration of the First and Second Coordination Spheres

55. Summary

56. Nickel-Catalyzed Reductive Couplings and Cyclizations

57. Introduction

58. Couplings of Alkynes with α,β-Unsaturated Carbonyls

59. Couplings of Alkynes with Aldehydes

60. Conclusions and Outlook

61. Copper-Catalyzed Ligand Promoted Ullmann-Type Coupling Reactions

62. Introduction

63. C–N Bond Formation

64. C–O Bond Formation

65. C–C Bond Formation

66. C–S Bond Formation

67. C–P Bond Formation

68. Conclusion

69. Copper-Catalyzed Azide-Alkyne Cycloaddition (CuAAC)

70. Introduction

71. Azide–Alkyne Cycloaddition: Basics

72. Copper-Catalyzed Cycloadditions

73. “Frustrated Lewis Pairs”: A Metal-Free Strategy for Hydrogenation Catalysis

74. Phosphine–Borane Activation of H₂

75. “Frustrated Lewis Pairs”

76. Metal-Free Catalytic Hydrogenation

77. Future Considerations

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Tags: Morris Bullock, Precious Metals