A Textbook of Physical Chemistry Thermodynamics And Chemical Equilibrium SI Unit 5e Volume 2 5th Edition by Kapoor ISBN 978-9339218911 9339218914
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A Textbook of Physical Chemistry Thermodynamics And Chemical Equilibrium SI Unit 5e Volume 2 5th Edition by K. L. Kapoor- Ebook PDF Instant Download/Delivery: 978-9339218911, 9339218914
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Product details:
ISBN 10: 9339218914
ISBN 13: 978-9339218911
Author: K. L. Kapoor
Table of contents:
1. Introduction to Physical Chemistry
– Definition and scope of physical chemistry
– Basic concepts: matter, energy, and thermodynamics
2. Gaseous State
– Ideal gases and the ideal gas law
– Real gases: deviations from ideality
– Van der Waals equation and critical phenomena
– Kinetic theory of gases
– Maxwell-Boltzmann distribution
3. Thermodynamics
– First Law of Thermodynamics: internal energy, heat, and work
– Enthalpy, heat capacities, and thermochemistry
– Second Law of Thermodynamics: entropy and spontaneity
– Gibbs and Helmholtz free energy
– Criteria for equilibrium and spontaneity
– Third Law of Thermodynamics
4. Thermochemistry
– Standard enthalpy changes
– Hess’s law and bond enthalpy
– Calorimetry and heat measurements
5. Chemical Equilibrium
– Law of mass action and equilibrium constants
– Le Chatelier’s principle
– Temperature dependence of equilibrium constants
– Phase equilibria and the phase rule
Solutions and Colligative Properties
– Types of solutions and concentration units
– Raoult’s law and ideal solutions
– Non-ideal solutions and activity coefficients
– Colligative properties: lowering of vapor pressure, elevation of boiling point, depression of freezing point, and osmotic pressure
7. Electrochemistry
– Electrochemical cells and cell potentials
– Nernst equation
– Standard electrode potentials and electrochemical series
– Electrolysis and Faraday’s laws
– Conductance of electrolytic solutions
Chemical Kinetics
– Rate of reaction and rate laws
– Order and molecularity of reactions
– Integrated rate equations for different orders
– Theories of reaction rates: collision theory and transition state theory
– Catalysis and enzyme kinetics
9. Surface Chemistry
– Adsorption and adsorption isotherms
– Catalysis at surfaces
– Colloidal systems and properties
– Emulsions and gels
10. Quantum Chemistry
– Origins of quantum theory: Planck’s hypothesis and the photoelectric effect
– Wave-particle duality and de Broglie’s hypothesis
– Schrödinger’s equation and its applications
– Quantum mechanical model of the hydrogen atom
– Quantum numbers and atomic orbitals
11. Statistical Thermodynamics
– The concept of microstates and macrostates
– Boltzmann distribution law
– Partition function and its significance
– Applications of statistical thermodynamics
12. Spectroscopy
– Interaction of radiation with matter
– Basic principles of molecular spectroscopy
– Rotational, vibrational, and electronic spectra
– NMR and ESR spectroscopy
Molecular Structure and Bonding
– Valence bond theory (VBT) and molecular orbital theory (MOT)
– Hybridization and molecular shapes
– Bonding in diatomic molecules
– Intermolecular forces
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