Analysis of Engineering Design Studies for Demilitarization of Assembled Chemical Weapons at Blue Grass Army Depot 1st Edition by National Research Council, Division on Engineering and Physical Sciences, Board on Army Science and Technology, Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II – Ebook PDF Instant Download/Delivery: 9780309085281, 0309085284
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Product details:
ISBN 10: 0309085284
ISBN 13: 9780309085281
Author: National Research Council, Division on Engineering and Physical Sciences, Board on Army Science and Technology, Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II
The U.S. Army is in the process of destroying the nation’s stockpile of aging chemical weapons stored at eight locations in the continental United States and on Johnston Atoll in the Pacific. Originally, incineration was chosen for the destruction of these stores, but this method has met with public opposition, and Congress directed the Army to develop alternative technologies for destroying the stockpiles in Pueblo, CO and Richmond, KY. To assist the Army in this process, the NRC was asked to evaluate the engineering design study of the three Blue Grass candidates. This book presents an analysis of various issues pertaining to the proposed engineering design package for the Blue Grass facility.
Table of contents:
1 INTRODUCTION
2 Background
3 Role of the National Research Council
4 Description of the Stockpile at Blue Grass Army Depot
5 Agents
6 Containers and Munitions
7 Statement of Task
8 Scope and Approach of This Study
9 Organization of This Report
10 HYDROLYSIS TESTS OF ENERGETIC MATERIALS
11 Overview of the Test Program
12 Testing at the Holston Army Ammunition Plant
13 Bench-scale Tests at Los Alamos National Laboratory
14 Results of the Test Program at the Holston Army Ammunition Plant
15 Process Controls
16 Gaseous Products of Hydrolysis
17 Hyrolysate Analyses
18 Results of the Test Program at Los Alamos National Laboratory
19 Composition B-4 and Tetrytol Hydrolysis
20 Propellant Hydrolysis
21 Rayon Cloth Treatment with Caustic
22 The Possible Formation of Lead Picrate
23 Summary Assessment
24 Findings and Recommendations
25 Findings
26 Recommendations
27 AEA SILVER IITM TECHNOLOGY PACKAGE
28 Description of the Process
29 Disassembly of Munitions
30 Preparation of Energetic Materials for SILVER IITM Process
31 Preparation of Agent for SILVER IITM Treatment
32 Treatment of Agent and Energetics by the SILVER IITM Process
33 Processing and Treatment of Metal Parts, Dunnage, and Other Solid Waste
34 Processing and Treatment of Gaseous Effluent Streams
35 Effluent Management
36 Information Used in Developing the Assessment
37 Engineering Design Package
38 Overview of Engineering Design Studies and Tests
39 Engineering Tests
40 Laboratory-Scale Testing
41 Desktop Studies
42 CST/CATOX Unit Testing
43 Assessment of Process Component Design
44 Disassembly of Munitions
45 Preparing Energetics for Destruction
46 Agent and Energetics Destruction
47 Separation of Agent from Munition Bodies
48 Agent Preparation for Destruction
49 Metal Parts Treatment
50 Dunnage Preparation and Treatment
51 Catalytic Oxidation Units
52 Assessment of Integration Issues
53 Component Integration
54 Process Operability
55 Materials of Construction
56 Maintenance Issues
57 Process Safety
58 Worker Health and Safety
59 Public Safety
60 Human Health and the Environment
61 Environmental Compliance and Permitting
62 Assessment of Overarching Technical Issues
63 Overall Engineering Design Package
64 Reevaluation of Steps Required for Implementation
65 Findings and Recommendations
66 Findings
67 Recommendation
68 ECO LOGIC TECHNOLOGY PACKAGE
69 Introduction and Overview
70 Description of the Process
71 Area 100-Reverse Assembly/Munitions Access
72 Area 200-Hydrolysis of Agent and Energetics
73 Area 300 Supercritical Water Oxidation
74 Area 400 Gas-Phase Chemical Reduction
75 Area 500 Utilities
76 Area 600 Materials Handling
77 Information Used in Developing the Assessment
78 Engineering-Design-Related Documents
79 Overview of Engineering Design Studies and Tests
80 Engineering Tests
81 Assessment of Process Component Design
82 Disassembly of Munitions and Removal of Agent and Energetics Area 100
83 Hydrolysis of Agent and Energetics Area 200
84 Supercritical Water Oxidation Area 300
85 Gas-Phase Chemical Reduction Area 400
86 Utilities Area 500
87 Materials Handling Area 600
88 Assessment of Integration Issues
89 Component Integration
90 Process Operability
91 Maintenance Issues
92 Monitoring and Control Strategy
93 Process Safety
94 Worker Health and Safety
95 Public Safety
96 Human Health and the Environment
97 Environmental Compliance and Monitoring
98 Assessment of Overarching Technical Issues
99 Steps Required Before Implementation
100 Findings and Recommendations
101 Findings
102 Recommendations
103 GENERAL ATOMICS TECHNOLOGY PACKAGE
104 Description of the Process
105 Disassembly of Munitions
106 Hydrolysis of Energetic Materials
107 Cryofracture of Munitions
108 Aluminum Precipitate Filtration
109 Projectile Rotary Hydrolyzer
110 Dunnage Hydropulping
111 Completion of Agent Hydrolysis
112 Treatment by Supercritical Water Oxidation
113 Treatment of Metal Parts
114 Water Recovery and Salt Disposal
115 Design and Throughput Basis for the GATS
116 Information Used in Developing the Assessment
117 Engineering-Design-Related Documents
118 Overview of Engineering Design Studies and Tests
119 Engineering Tests
120 Assessment of Process Component Design
121 Disassembly of Munitions Steps 1 3 4 6
122 Hydrolysis of Energetic Materials Steps 5 7 and 15
123 Processing and Treatment of Dunnage and Energetics
124 Hydrolysate Steps 2 and 9
125 Agent Hydrolysis and Treatment of Metal Parts Steps 8 10 13 and 16
126 Treatment of Hydrolysates and Dunnage by Supercritical Water Oxidation Steps 11 12 and 14
127 Assessment of Integration Issues
128 Component Integration
129 Process Operability
130 Monitoring and Control Strategy
131 Maintenance Issues
132 Process Safety
133 Worker Health and Safety
134 Public Safety
135 Human Health and the Environment
136 Assessment of Overarching Technical Issues
137 Overall Engineering Design Package
138 Steps Required Before Implementation
139 Findings and Recommendations
140 Findings
141 Recommendations
142 GENERAL FINDINGS
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Tags: National Research Council, Division on Engineering and Physical Sciences, Board on Army Science and Technology, Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II


